Thermodynamics


  1. The internal energy change in a system that has absorbed 2 kcals of heat and done 500 J of work is :









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    According to first law of thermodynamics ​Q = ∆U + W
    ∆U = Q – W
    ​= 2 × 4.2 × 1000 – 500
    = 8400 – 500 ​= 7900 J

    Correct Option: C

    According to first law of thermodynamics ​Q = ∆U + W
    ∆U = Q – W
    ​= 2 × 4.2 × 1000 – 500
    = 8400 – 500 ​= 7900 J


  1. An ideal gas goes from state A to state B via three different processes as indicated in the P-V diagram :

    If Q1 , Q2 , Q3 indicate the heat a absorbed by the gas along the three processes and ∆U1 , ∆U2 , ∆U3 indicate the change in internal energy along the three processes respectively, then









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    Initial and final condition is same for all process ​
    ∆U1​ = ∆U2 = ∆U3
    from first law of thermodynamics ​∆Q = ∆U + ∆W ​
    Work done ​∆W1 > ∆W2 > ∆W3 (Area of P.V. graph)
    ​So ∆Q1 > ∆Q2 > ∆Q3

    Correct Option: A

    Initial and final condition is same for all process ​
    ∆U1​ = ∆U2 = ∆U3
    from first law of thermodynamics ​∆Q = ∆U + ∆W ​
    Work done ​∆W1 > ∆W2 > ∆W3 (Area of P.V. graph)
    ​So ∆Q1 > ∆Q2 > ∆Q3



  1. A system is taken from state a to state c by two paths adc and abc as shown in the figure. The internal energy at a is Ua = 10 J. Along the path adc the amount of heat absorbed δQ1 = 50 J and the work done δW1 = 20 J whereas along the path abc the heat absorbed δQ2 = 36 J. The amount of work done along the path abc is









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    From first law of thermodynamics​ ​​​
    Qadc​ =​ ∆Uadc​ + Wadc
    50 J​ =​ ∆Uadc​ + 20 J ​​​
    ∆Uadc​ ​=​ 30 J ​
    Again ,​ Qabc​ ​=  ∆Uabc​ + Wabc​ ​​​
    Wabc​​ =​ Qabc​ – ∆Uabc​ ​​​​
    =​ Qabc​ – ∆Uadc​ ​​​​
    = ​36 J – 30 J ​​​​=​ 6 J

    Correct Option: A

    From first law of thermodynamics​ ​​​
    Qadc​ =​ ∆Uadc​ + Wadc
    50 J​ =​ ∆Uadc​ + 20 J ​​​
    ∆Uadc​ ​=​ 30 J ​
    Again ,​ Qabc​ ​=  ∆Uabc​ + Wabc​ ​​​
    Wabc​​ =​ Qabc​ – ∆Uabc​ ​​​​
    =​ Qabc​ – ∆Uadc​ ​​​​
    = ​36 J – 30 J ​​​​=​ 6 J


  1. The coefficient of performance of a refrigerator is 5. If the inside temperature of freezer is –20°C, then the temperature of the surroundings to which it rejects heat is​​​









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    Coefficient of performance, Cop =
    T2
    T1 - T2

    5 =
    273 - 20
    =
    253
    T1 - (273 - 20)T1 - 253

    5T1 – (5 × 253) = 253​ ​
    5T1 = 253 + (5 × 253) = 1518
    ∴ T1 =
    1518
    = 303.6
    5

    or, T1 = 303.6 – 273 = 30.6 ≅ 31°C

    Correct Option: D

    Coefficient of performance, Cop =
    T2
    T1 - T2

    5 =
    273 - 20
    =
    253
    T1 - (273 - 20)T1 - 253

    5T1 – (5 × 253) = 253​ ​
    5T1 = 253 + (5 × 253) = 1518
    ∴ T1 =
    1518
    = 303.6
    5

    or, T1 = 303.6 – 273 = 30.6 ≅ 31°C



  1. The efficiency of a Carnot engine operating between the temperatures of 100°C and –23°C will be​​









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    η = 1 -
    T1
    T2

    T1 = –23°C = 250 K ,   T2 = 100°C = 373K
    η = 1 -
    250
    =
    373 - 250
    373373

    Correct Option: C

    η = 1 -
    T1
    T2

    T1 = –23°C = 250 K ,   T2 = 100°C = 373K
    η = 1 -
    250
    =
    373 - 250
    373373