Thermodynamics


  1. During an isothermal expansion, a confined ideal gas does –150 J of work against its surroundings. This implies that​











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    If a process is expansion then work done is positive so answer will be (a). ​
    But in question work done by gas is given –150J so that according to it answer will be (d).

    Correct Option: E

    If a process is expansion then work done is positive so answer will be (a). ​
    But in question work done by gas is given –150J so that according to it answer will be (d).


  1. If ∆U and ∆W represent the increase in internal energy and work done by the system respectively in a thermodynamical process, which of the following is true?​









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    By first law of thermodynamics, ​ ​
    ∆Q = ∆U - ∆W
    In adiabatic process, ∆Q = 0 ​​ ​
    ∴ ∆U = -∆W
    In isothermal process, ∆U = 0 ​​
    ∴ ∆Q = ∆W

    Correct Option: A

    By first law of thermodynamics, ​ ​
    ∆Q = ∆U - ∆W
    In adiabatic process, ∆Q = 0 ​​ ​
    ∴ ∆U = -∆W
    In isothermal process, ∆U = 0 ​​
    ∴ ∆Q = ∆W



  1. In thermodynamic processes which of the following statements is not true?​​









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    ​In an isochoric process volume remains constant whereas pressure remains constant in isobaric process.

    Correct Option: A

    ​In an isochoric process volume remains constant whereas pressure remains constant in isobaric process.


  1. If Q, E and W denote respectively the heat added, change in internal energy and the work done in a closed cyclic process, then :​









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    In a cyclic process, the initial state coincides with the final state. Hence, the change in internal energy is zero, as it depends only on the initial and final states. But Q & W are non-zero during a cycle process.

    Correct Option: C

    In a cyclic process, the initial state coincides with the final state. Hence, the change in internal energy is zero, as it depends only on the initial and final states. But Q & W are non-zero during a cycle process.



  1. One mole of an ideal gas at an initial temperature of T K does 6R joules of work adiabatically. If the ratio of specific heats of this gas at constant pressure and at constant volume is 5/3, the final temperature of gas will be​​









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    T1 = T , W = 6R joules , γ =
    5
    3

    W =
    P1V1 - P2V2
    =
    nRT1 - nRT2
    γ - 1γ - 1

    =
    nR(T1 - T2)
    γ - 1

    n = 1 , T1 = T ⇒
    R(T - T2)
    = 6R
    (5 / 3) - 1

    ⇒ T2 = ( T–4)K

    Correct Option: A

    T1 = T , W = 6R joules , γ =
    5
    3

    W =
    P1V1 - P2V2
    =
    nRT1 - nRT2
    γ - 1γ - 1

    =
    nR(T1 - T2)
    γ - 1

    n = 1 , T1 = T ⇒
    R(T - T2)
    = 6R
    (5 / 3) - 1

    ⇒ T2 = ( T–4)K