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A researcher conducts electrochemical machining (ECM) on a binary alloy (density 6000 kg/m3) of iron (atomic weight 56, valency 2) and metal P (atomic weight 24, valency 4). Faraday's constant = 96500 coulomb/mole. Volumetric material removal rate of the alloy is 50 mm3/s at a current of 2000 A. The percentage of the metal P in the alloy is closest to
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- 40
- 25
- 15
- 79
Correct Option: B
Given data:
ρ = 6000 kg /m3 = 6 gm/cc.
MRR (Q) = 50 mm3 /s
50 × 10–3 CC/S
MRR = | |
ρZF |
50 × 10–3 = | |
96500 × 6 |
e = 14.475
and for Iron Atomic weight
AFE = 56, Valency: rFe = 2
For metal P, at weight
(At)p = 24, Valency rp = 4
Now, let% of P in alloy = x.
= | × | + | × | |||||
e | 100 | AP | 100 | AFet |
= | × | + | ![]() | ![]() | |||||
14.75 | 100 | 27 | 56 | 100 |
x = 24.48 ≈ 25