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  1. Temperature of nitrogen in a vessel of volume 2 m3 is 288 K. A U-tube manometer connected by the vessel shows a reading of 70 cm of mercury (level higher in the end open to atmosphere). The universal gas constant is 8314 J/kmol-K, atmospheric pressure is 1.01325 bar, acceleration due to gravity is 9.81 m/s2 and density of mercury is 13600 kg/m3. The mass of nitrogen (in kg) in the vessel is _______.
    1. 4.55
    2. 5.55
    3. 4.65
    4. 4.59
Correct Option: A

p =ρgh = 0.7 × 1360 × 9.81 = 9339.12Pa
Actual pressure = atmospheric pressure = 110664.12 Pa
pv =mRT ⇒ m = pv/RT

m =
110664.12 × 2
⇒ m = 4.55kg
288 × 8314



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